Concrete degradation happens through time. It is accelerated by using reactive materials and exposure to various conditions. Different types of deterioration can be observed using concrete petrography.
THE DIFFERENT DETERIORATION PHASES OF CONCRETE
Cracks can be an indication of concrete deterioration. Proper assessment and investigation of cracks is very important to assure the safety and soundness of the structure.
WHAT ARE THE DIFFERENT FORMS AND CAUSES OF CRACKS?
Structural Cracks
This can be caused by incorrect design, faulty construction, overloading, poor soil bearing, swollen soil, and poor construction sites. It can be found in the column, beam, joist, slab or wall and may be dangerous based on its severity. Structural engineers must examine the damaged part in order to assess the integrity of the structure.
Scaling and Exfoliation
Scaling and exfoliation happens on the surface and can be observed as the peeling off or flaking of a certain part of the exterior concrete or mortar. This can be caused by the penetration of expansive agents. Freeze/thaw attacks, sulphate solutions, salt recrystallization and near surface corrosion of steel reinforcements.
Popouts
Popouts can leave a small crater in the concrete and can reach a diameter of 100 mm and depth of 40 mm. It starts of as a semicircular crack progressing to an inverted cone. The portion of the concrete that breaks may include a remnant of the aggregate. It happens due to the presence of expansive materials such as alkali silica gel, iron sulphide minerals and freeze/thaw attack in aggregates.
Mapcracking
Also known as pattern cracking, this type of crack forms a network of fine cracks extending through the upper concrete surface. Expansion caused by alkali-silica reaction (ASR), drying shrinkage and restrained thermal contraction are some of its causes.
Shrinkage cracks
Moisture change in concrete is the primary cause of shrinkage cracks. Presence of shrinkable aggregates, plastic & drying shrinkage and bleeding in concrete are some causes.
Expansion cracks
Cracks are formed once the expansion in concrete can’t be accommodated anymore. It can be due to the expansion brought by reformation of ettringite, alkali-aggregate reactions, reinforcement corrosion, thermal gradient from the environment, freeze/thaw attacks and salt recrystallization.
METHODS FOR CRACK REPAIR:
Resin injection
Dry packing
Stitching and Bandaging
Muting and sealing
Drilling and plugging
Vacuum impregnation and Polymer impregnation
Autogenously healing
Flexible sealing
References:
Poole, A. B., & Sims, I. (2016). Concrete Petrography: A Handbook of Investigative Techniques (2nd ed.). CRC PRESS.
https://www.chamberlinltd.com/consultants-corner-repairing-cracked-concrete/
https://ohiobasementauthority.com/difference-between-structural-cracks-and-non-structural-foundation-cracks/
https://www.tarmac.com/media/960524/non-structural-cracking-leaflet-a4-sbn-0419.pdf
https://theconstructor.org/concrete/prevent-cracks-in-concrete-structures/13457/
Also known as "Concrete Cancer", ASR or Alkali-Silica reaction is a progressive form of deterioration that can be observed in concrete. It produces a gel-like material which expands once it is exposed to moisture. This can produce additional volume and strain to the hardened concrete and may lead to cracking.
HOW DOES IT FORM?
There are three main components for the reaction to proceed:
1. Presence of reactive aggregates
These are aggregates that contain reactive silica or amorphous silica which may react with the highly alkaline pore solution. Examples of reactive silica are cryptocrystalline silica, unstable varieties of quartz and volcanic glass.
2. Alkali concentration in the pore solution
The sodium and potassium ions present in the alkaline concrete pore fluid will interact and attack the varieties of silica present in the concrete. This will produce the alkali-silica gel.
3. Moisture availability
Exposure to moisture will trigger the expansion and swelling of the alkali silica gel. It will absorb the water into their structure and will expand causing strain to the concrete which will eventually lead to cracking if left unchecked.
Prevention of Alkali-Silica Reaction
1. Proper selection of aggregates
2. Usage of low-alkali cement
3. Fixing the water access and preventing exposure to moisture
4. The use of admixtures such as lithium and barium salts
5. Partial replacement of cement
References:
Alkali Silica Reaction - Proactive Avoidance. (n.d.). Retrieved from https://www.engr.psu.edu/ce/courses/ce584/concrete/library/chemical/asrproact.html
Alkali-Aggregate Reaction. (n.d.). Retrieved from https://www.cement.org/learn/concrete-technology/durability/alkali-aggregate-reaction
Poole, A. B., & Sims, I. (2016). Concrete Petrography: A Handbook of Investigative Techniques (2nd ed.). CRC PRESS.
Ettringite is a normal product of early cement hydration. All of it should be transformed to another more stable material after several days. Delayed ettringite formation (DEF) happens if high temperatures (>65 °C) during the curing of concrete interrupt the transformation. When the concrete has hardened and there is excess sulfate ions plus moisture in the environment, DEF occurs.
WHERE DOES IT USUALLY FORM?
DEF can occur in cracks, along aggregate boundaries and in air voids. This could result to expansion which can damage concrete structures. It appears as needle-like crystals under the microscope.
References:
Poole, A. B., & Sims, I. (2016). Concrete Petrography: A Handbook of Investigative Techniques (2nd ed.). CRC PRESS.
Carbonation of hardened cement matrix is a result of the reaction between the atmospheric carbon dioxide and the components of the cement specifically the calcium hydroxide and the cement hydrates.
HOW DOES THE REACTION PROCEED?
These are the chemical reactions that take place:
Ca(OH)2 + CO2 → CaCO3 +H2O
Calcium silicate hydrate + CO2 → various intermediates → CaCO3 + SiO2•nH2O + H2O
Aluminate hydrates + CO2 → CaCo3 + hydrated alumina
Ferrite hydrates + CO2 → CaCO3 + hydrated alumina and iron oxides
Carbonation and Corrosion
The alkalinity of concrete protects and preserves the thin passive layer on steel reinforcements. The steel is protected from corrosion due to the concrete having a pH of around 12.5. However, carbonation of the cement paste lowers the pH of the pore solution. This will be a problem to steel reinforcements due to the acidic conditions. Carbonated concrete has a pH around 9.5 which could cause the thin film protecting the steel to be damaged thereby making it vulnerable to corrosion.
Prevention and Mitigation
Make a denser well compacted concrete having low water/cement ratio to reduce the porosity and permeability of the cement paste
Coat the surface of the concrete
Regularly monitor the surface cracks
Apply penetrating sealers in areas where carbonation are observed to prevent further deterioration of the concrete.
References:
Poole, A. B., & Sims, I. (2016). Concrete Petrography: A Handbook of Investigative Techniques (2nd ed.). CRC PRESS.
https://theconstructor.org/concrete/carbonation-of-concrete-structures/7791/
https://www.understanding-cement.com/carbonation.html